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Question

250 mL of 0.5 M NaOH was added to 500 mL of 1M HCl.The number of unreacted HCl molecules in the solution after compelete reaction is x×1021. The value of x to the nearest integer is
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(NA=6.022×1023)

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Solution

Millimoles of NaOH=250×0.5=125

Millimoles of HCl=500×1=500
Now reaction is
NaOH+HClNaCl+H2Ot=0 125 500 t=t 0 375 125 125
So millimoles left of HCl=375
Moles of HCl=375×103
No.of HCl molecules
=6.022×1023×375×103
=225.8×1021
226×1021
value of x is 226

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