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Electrolytic Refining

27. in pcl fi...

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27. in pcl five decomposition at final mole why will not take two mines to alpha

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What will be the hypridisation of P when PCl₅ undergoes thermal decomposition..!?

{P C l}_{5} (g) ⇌ {P C l}_{3} (g) + {C l}_{2} (g)

In above reaction, at equilibrium condition mole fraction of

{P C l}_{5}

0.4

and mole fraction of

{C l}_{2}

0.3

. Then find out mole fraction of

{P C l}_{3}

?

Q. In the reaction

{P C l}_{5} ⇋ {P C l}_{3} + {C l}_{2}

, the amount of each

{P C l}_{5}, {P C l}_{3} a n d {C l}_{2}

2 m o l e

at equilibrium and total pressure is

3

atmosphere. The value of

K_{p}

Q. Five moles of an ideal gas at

27^{o} C

are allowed to expand isothermally from an initial pressure of 10.0 atm to a final pressure of 4.0 atm against a constant external pressure of 1.0 atm. Thus, work done will be:

P C l_{5} (g)

dissociates and attains equilibrium after t seconds at

27^{\circ} C

P C l_{5} (g) ⇋ P C l_{3} (g) + C l_{2} (g)

At equillibrium, the vapour density is found to be 100 and the volume of the system is 10.425 L at

27^{\circ} C

.
The total pressure of the system at equilibrium will be atm.

R = 0.082 L a t m m o l^{- 1} K^{- 1}

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