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Extraction of Zinc

29.why the hy...

Question

29.why the hybridisation of [Cu(NH3)4]+2 is sp2d and not dsp2

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[C u (N H_{3})_{4}]^{2 +}

is coloured while

[C u (C N)_{4}]^{3 -}

is colourless. Reason:

[C u (N H_{3})_{4}]^{2 +}

d s p^{2}

Q. Why a p orbital is left unhybridised in sp2d hybridisation?

[N i (C O)_{4}]

[N i (C N)_{4}]^{2 -}

are diamagnetic. The hybridisation of nickel in these complexes, respectively are:

Q. The hybridised state of

C u

[C u (N H_{3})_{4}]^{2 +}

The correct order of hybridisation of the central atom in the following species $N H_{3}$ , ${[P t C l_{4}]}^{2 -}$ , $P C l_{5}$ and $B C l_{3}$

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