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Question

2A(g)+3B(g)+C(g)D(g)+E(g)
The order of the given reaction is 72 and the experimental rate law of the given reaction is K[A]2[B]x[C]1. Find the value of 'x'.

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Solution

Order of a reaction:
For a given reaction:
aA+bB+cCProducts
If,
Rate[A]p[B]q[C]r
Overall order of the reaction is :
(p+q+r)

So, for
2A(g)+3B(g)+C(g)D(g)+E(g)

The experimental rate law is,
R=K[A]2[B]x[C]1

Thus, the overall order of the reaction is
(2+x+1)

Order of given reaction is 72

2+x+1=72
x=723
x=12
Thr order of reaction with respect to B is 12

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