Dynamic Nature of Physical and Chemical Equilibrium
2H2Sg + 3O2g ...
Question
2H2S(g)+3O2(g)→2SO2(g)+2H2O(g)+ heat
Which quantity is increased when the volume of the system is decreasing ? I. Rate of reaction II. Equilibrium concentration of reactants III. Value of Keq
A
I only
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B
III only
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C
I and II only
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D
II and III only
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E
I, II, and III
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Solution
The correct option is A I only When the volume of the reaction system is decreased, the rate of the reaction is increased. The value of the equilibrium constant will remain unchanged and the equilibrium concentrations of reactants will decrease and products will increase. With decrease in the volume, the number of moles of reactant per unit volume increases. This increases the reactant concentration and the rate of the reaction.