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Question

2mol of N2 is mixed with 6 mol of H2 in a closed vessel of one litre capacity. If 50% N2 is converted into NH3 at equilibrium, the value of Kc for the reaction.
N2(g)3H2(g)2NH3(g) is:

A
4/27
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B
27/4
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C
2/27
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D
20
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Solution

The correct option is A 4/27

N2+3H22NH2

2 moles of N2 will react with 6 moles of H2 and 2 moles of N2 gives 4 moles of NH3 But (50 of N2 only reacts)

Hence 1 mole of N2 gives 2 moles of NH3

N2+3H22NH2

Initial 2 6 0

Eq 1 3 2

Kc =[NH3]2[N2][H2]3=2233=427


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