3.5 g of a fuel (having molecular weight 28), was burnt in a caloriemeter and raised the temperature of 1 g of water from 25∘C to 67.3∘C. If all the heat generated was used in heating water, calculate the magnitude of molar heat of combustion of fuel in calmol−1.
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Solution
Amount of fuel used = 3.5g28gmol−1=0.125mol So the energy generated, Cp(water)×increaseintemperature×amountofwatering =1cal/goC×42.30oC×1g=42.3cal So, the molar heat of combustion, 42.30.125calmol−1=338.4calmol−1