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Question

3.5 g of a fuel (having molecular weight 28), was burnt in a caloriemeter and raised the temperature of 1 g of water from 25C to 67.3C. If all the heat generated was used in heating water, calculate the magnitude of molar heat of combustion of fuel in calmol1.

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Solution

Amount of fuel used = 3.5 g28 gmol1=0.125 mol
So the energy generated, Cp(water)×increase in temperature×amount of water in g
=1cal/goC×42.30 oC×1 g=42.3 cal
So, the molar heat of combustion, 42.30.125 calmol1=338.4 calmol1

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