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Question

3-Nitroaniline is subjected to the treatment of various reagents in the following sequences.
(i) NaNO2/HCl,280K
(ii) KI
(iii) Cu powder
The final product will be:

A
3,3 diaminobiphenyl
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B
3,3-dinitrobiphenyl
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C
3- nitroiodobenzene
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D
3-iodoaniline
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Solution

The correct option is B 3,3-dinitrobiphenyl
Final step is Ullmann reaction or Ullmann coupling is a coupling reaction between aryl halides and copper.

The final product in the given sequence of reactions is 3,3diaminobiphenyl.

Option B is correct.

733944_642057_ans_9e23b538301f4efd972dbc90939928e5.png

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