30.0 mL of the given HCl solution requires 20.0 mL of 0.1 M sodium carbonate solution for complete neutralisation. What is the volume of this HCl solution required to neutralise 30.0 mL of 0.2 M NaOH solution?
A
25 mL
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B
50 mL
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C
90 mL
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D
45 mL
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Solution
The correct option is D 45 mL (N×V)HCl=(N×V)sodiumcarbonate NHCl×30=Molarity×nf×20 nf for sodium carbonate =2 NHCl×30=0.1×2×20 NHCl=430 when HCl neutralises with NaOH: (N×V)HCl=(N×V)NaOH (430×V)HCl=(1×0.2×30)NaOH VHCl=45mL