30mL of N/10HCl is required to neutralise 50mL of a sodium carbonate solution. How many mL of water must be added to 30mL of this solution so that the solution obtained may have a concentration equal to N/50?
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Solution
Given,
VHCl=30ml, NHCl=N10=0.1N
NNa2CO3=?VNa2CO3=50mL
(V×N)Na2CO3=(V×N)HCl
NNa2CO3=30×0.150
=0.06N
Again, 30mL of 0.06NNa2CO3 is made to N50=0.02N
N1V1=N2V2
V2=N1V1N2=0.06×300.02=90 mL$
90mL of water should be zadded to get 0.02N solution.