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Question

300 mL of 5×102M HCl is allowed to react with 200 mL of 5×102M NaOH at 300K. The pH of the resulting solution at 300K is

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Solution

The number of moles of hydrogen ions present in HCl solution
=0.3L×0.05mol/L=0.015mol
The number of moles of hydroxide ions present in NaOH solution
=0.2L×0.05mol/L=0.010mol
The number of moles of hydrogen ions remaining after neutralization
0.015mol0.010mol=0.005mol
Total volume =0.5L
[H+]=0.005mol0.5L=0.01M
pH=log[H+]
=log0.01
=2

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