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Question

300 mL of H2SO4 solution of certain molarity was mixed with 200 mL of a Ba(OH)2 solution of same molarity. The pH of the mixture solution is 1. The normality of H2SO4 and Ba(OH)2 is x×101N, where x is:

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Solution

The pH of the mixture is 1.
Hence, the hydrogen ion concentration and the normality of the resulting solution is 0.1N.

Let n be the normality of sulfuric acid and barium hydroxide solution.

The normality of the resulting solution is given by the expression NaVaNbVbVa+Vb.

Substituting values in the above expression, we get-

0.1=n×300n×200300+200

Thus, n=0.5N=5×101N.

Hence, the value of x is 5.

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