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Comparison of Physisorption and Chemisorption

34. For [Ag (...

Question

34. For [Ag (NH3)2]+ at 298K at 10 dissociation constant in Ag+&NH3 If E^° Ag+/Ag=0.8V so what is E^° value of half cell [Ag(NH3)2]+ +e.>Ag+ +2NH3 1)0.33V 2)0.33V 3)0.033V 4)0.033V

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E^{\circ}

298 K

A g (N H_{3})_{2}^{+} + e^{-} \to A g + 2 N H_{3}

A g^{+} + e^{-} \to A g; E_{A g^{+} / A g}^{\circ} = 0.80 V

A g (N H_{3})_{2}^{+} ⇌ A g^{+} + 2 N H_{3}; K = 6 \times 10^{- 8}

K_{d}

[A g (N H_{3})_{2}]^{+}

A g^{+}

N H_{3}

6 \times 10^{- 8}

E^{\circ}

A g (N H_{3})_{2}^{+} + e^{-} \to A g + 2 N H_{3}

A g^{+} + e^{-} \to A g, E^{\circ} = 0.799 V

A g (N H_{3})_{2}^{+} \to A g^{+} + N H_{3}

6 \times 10^{14}

A g (N H_{3})_{2}^{+} + e \to A g + 2 N H_{3}

E^{o} A g^{+} / A g = 0.799 V

E^{o}

[A g (N H_{3})_{2}]^{+} ⇌ A g^{+} + 2 N H_{3}

6 \times 10^{- 14} .

E^{o}

y \times 10^{- 3} e V

[A g (N H_{3})_{2}]^{+} + e^{-} \to A g + 2 N H_{3}

A g^{+} + e^{-} \to A g; E^{0} = 0.799 V

A g (N H_{3})_{2}^{+}

A g^{+}

N H_{3}

6 \times 10^{- 14}

E^{o}

A g (N H_{3})_{2}^{+} + e \to A g + N H_{3}

A g^{+} + e \to A g; E^{o} = 0.799 V

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