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Anionic Radius

35.which meta...

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35.which metal ion is likely to form a square planar Complex Ion with CN - Cu+ Ag+ Ni+2 Zn+2

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Q. Given ions are :

F e^{2 +}, N i^{2 +}, C a^{2 +}, K^{+}, M g^{2 +}, N a^{+}, C u^{2 +}, Z n^{2 +}

.
If all the given ions can form complexes then enter 1, else enter 0.

Explain on the basis of valence bond theory that [Ni(CN)₄]²⁻ ion with square

planar structure is diamagnetic and the [NiCl₄]²⁻ ion with tetrahedral geometry is paramagnetic.

Q. Dimethyl glyoxime forms a square planar complex with

N i^{2 +}

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Q. Which of the following forms, with an excess of

C N^{-}

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Q. An aqueous solution of metal ion (X) reacts seperately with reagents A and B in excess to give tetrahedral and square planar complexes, respectively. An aqueous solution of another metal ion (Y) always form tetrahedral complexes with these reagents and on reaction with small amount of C reagent gives precipitate which dissolves in excess of C.

X, A, B respectively are:

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