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Oxyacids Of Sulphur

37. PF bond l...

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37. PF bond length in PF3 and POF3?

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Q. The correct increasing bond angle among

B F_{3}, P F_{3}

C I F_{3}

follows the order

The correct increasing bond angle among $B F_{3}, P F_{3}$ and $C l F_{3}$ follows the order

Q. Assertion :Bond angle in

P F_{3}

greater than the bond angle in

P H_{3}

Reason: Electrons in

P F_{3}

are displaced towards more electro-negative

F

P - F

Q. The decreasing order of bond angles in

B F_{3}, N H_{3}, P F_{3}

I_{3}^{-}

Q. Assertion :Bond angle of

{P F}_{3} > P {C l}_{3}

but bond angle of

P {C l}_{3} < P {B r}_{3}

Reason: The bond angles show an increase on decreasing electronegativity of attached other atom on central atom but in

{P F}_{3}

p π - d π

bonding results in an increase in bond angle.

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