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Melting and Boiling Points

39. Para dich...

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39. Para dichlorobenzene has higher melting point and solubility than those of ortho and meta isomer.why?

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1

: Paradichlorobenzene has higher melting point and solubility than that of ortho and meta forms.

2

: Para isomer has symmetrical structure and can easily pack closely in crystal structure.

Q. p-Dichlorobenzene has higher melting point than those of o- and m-isomers. Discuss.

Q. Assertion :The para-isomers have higher melting point as compared to their ortho and meta-isomers. Reason: It is due to symmetry of para-isomers that fits in crystal lattice better as compared to ortho- and meta-isomers.

Q. Ortho-nitrophenol is less soluble in water than para and meta-nitrophenols because:

Q. Which has a higher melting point between

1, 3 -

dichlorobenzene and

1, 4 -

dichlorobenzene?

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