$3 K C l O_{3} + 3 H_{2} S O_{4} \to 3 K H S O_{4} + H C l O_{4} + 2 C l O_{2} + H_{2} O$
If molecular weight of $K C l O_{3}$ is $M$ , then equivalent weight of $K C l O_{3}$ is:

\frac{M}{4}

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\frac{M}{2}

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\frac{3 M}{2}

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\frac{3 M}{4}

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Solution

The correct option is C $\frac{3 M}{2}$
Here $C l O_{3}^{-}$ undergoes both oxidation and reduction to form $C l O_{4}^{-}$ and $C l O_{2}$ .
$C l O_{3}^{-} \to C l O_{4}^{-} + 2 e^{-} (x = 2) Oxidation e^{-} + C l O_{3}^{-} \to C l O_{2} (x = 1) reduction E_{w} = M + \frac{M}{2} = \frac{3 M}{2}$

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Similar questions

3 K C l O_{3} + 3 H_{2} S O_{4} \to 3 K H S O_{4} + H C l O_{4} + 2 C l O_{2} + H_{2} O

K C l O_{3}

M

K C l O_{3}

3 K C l O_{3} + 3 H_{2} S O_{4} \to 3 K H S O_{4} + H C l O_{4} + 2 C l O_{2} + H_{2} O

K C l O_{3}

3 M n O_{2} - ------- - + 6 K O H + K C l O_{3} ⟶ 3 K_{2} M n O_{4} + K C l + 3 H_{2} O

M

H_{3} P O_{2}

P H_{3}

H_{3} P O_{3}

N a_{2} S_{2} O_{3}

N a_{2} S_{4} O_{6}

2 N a_{2} S_{2} O_{3} + I_{2} \to N a_{2} S_{4} O_{6} + 2 N a I

N a_{2} S_{2} O_{3}

N a_{2} S_{2} O_{3} = M)

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