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Question

4.90 g of KClO3, on heating shows a weight loss of 0.384g. What percentage of the original KClO3 has decomposed?

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Solution

2KClO3+heat2KCl+3O2
2mol KClO3 produce 3 mol O2
The 0.384 g mass loss was due to the oxygen generated.
The amount of moles of oxygen generated can be calculated as: Molar mass O2 = 32 g/mol
0.384 g O2 = 0.384/32 = 0.012 mol O2 generated
This came from the decomposition of 0.012 x 2/3 = 0.008 mol ofKClO3
Molar mass KClO3 = 122.55 g/mol
0.008 mol KClO3 = 0.008 x 122.55 = 0.9804 g KClO3 decomposed
% of original sample=0.98044.90×100=20%

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