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Shape and Geometry Using VSEPR

4. q-hybridis...

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4. q-hybridisation of Al in AlCl3 (monomeric form above 800C) and Al2Cl6(dimeric form below 400C) respectively are?

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Boron halides are monomeric while AlCl₃ forms dimer. Why?

B e C l_{2}

can exist in monomeric form, dimeric form as well as polymeric form. Identify the hybridisation of

B e

B e C l_{2}

Q. Describe the change in hybridisation (if any) of the

A l

atom in the following reaction:

A l C l_{3} + C l^{-} \to A l C l_{4}^{-}

B e C l_{2}

exist as dimer below 1200K and monomer above 1200K. Reason:

B e C l_{2}

is in dimeric form in vapour phase below 1200K.

Q. Describe the change in hybridisation of the

A l

atom in the following reaction :

A l C l_{3} + C l^{-} \to {A l C l_{4}}^{-}

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