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Curtius and Hofmann Rearrangements

40 Assertion:...

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40 Assertion: the decarboxylation of 3- Nitro butanoic acid is difficult than that of 3 -methyl butanoic acid. Reason: the carbanion formed is destabilized in 3-nitro butanoic acid.

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Q. Assertion :Sodium salt of butanoic acid on heating with soda lime gives butane. Reason: Decarboxylation reaction yields alkanes having same number of carbon atoms as the parent acid.

Q. The correct structural formula of butanoic acid is

Q. Arrange the following in order of increasing acidity.
2-Fluorobutanoic acid, 2-iodobutanoic acid, 2-bromobutanoic acid and butanoic acid

Q. Which of the compounds shown will react with dimethyl malonate in the presence of methoxide ion to give a compound, which on treatment with aqueous acid and gentle heating will decarboxylate to form butanoic acid?

Q. Kolbe's synthesis of sodium salt of butanoic acid gives:

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Curtius and Hofmann Rearrangements

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