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Nucleic Acids

40.Which is b...

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40.Which is better nucleophile NH2- or OH- in 1.DMF 2.CH3OH. with reasons.

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Q. In the following pair of compounds, which compound is more nucleophilic in a polar-protic solvent?

{C H}_{3} C l

{C H}_{3} O H

Q. Assertion :Tert-Butoxide is a stronger base than

O H^{-}

C_{2} H_{5} O^{-}

ion but is a much poorer nucleophile.

B e c a u s e

Reason: A negatively charged ions is always more powerful nucleophile than its conjugate acid.

Arrange in decreasing order of basicity,

$H_{2} O, O H^{-}, C H_{3} O H, C H_{3} O^{-}$

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