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Standard XII
Chemistry
Physisorption
43. Can chlor...
Question
43. Can chloral give cannizaro reaction?
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Q.
Assertion :When chloral is heated with concentrated potassium hydroxides, it yields
C
C
l
3
C
O
O
−
and
C
C
l
3
C
H
2
O
H
. Reason: In the cannizaro reaction, hydride transfer is the slowest step.
Q.
Some of following compounds can undergo intramolecular cannizaro reaction
Select the compounds undergoing intramolecular cannizaro reaction:
Q.
Give the decreasing order of nucleophilic addition reaction of the followings:
(i)
H
C
H
O
(ii)
P
h
C
H
O
(iii) Chloral
(
C
l
3
C
−
C
H
=
O
)
(iv) Acetophenone
Q.
A compound A with molecular formula
C
10
H
13
C
l
gives a white precipitate on adding silver nitrate solution. A on reacting with alcoholic KOH gives compound B as the main product. B on ozonolysis gives C and D. C gives Cannizaro reaction but not alodol condensation. D gives aldol condensation but not Cannizaro reaction. A is:
Q.
Assertion: Chloral forms stable Hydrate
Reason: On distilling with conc.
N
a
O
H
solution chloral hydrate gives pure chloroform and sodium formate.
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