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Van't Hoff Factor

45. Explain t...

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45. Explain the formation of cyanide and isocyanide ion with the help of structural diagram?What is the difference between the 2?

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N_{2} C O

has three possible structures:

O N C N

(nitrosyl cyanide),

O N N C

(nitrosyl isocyanide),

N O C N

(isnitrosyl cyanide)
Which of the following structure has lowest potential energy?

Q. The isomerism present in cyanide and isocyanide is:

Q. Assertion :Methyl cyanide has higher boiling point than methyl isocyanide. Reason: Dipole moment of methyl cyanide is higher than that of methyl isocyanide.

Q. Given below are two statements labelled as Assertion (A) and Reason (R).
Assertion (A): Treatment of chloroethane with a saturated solution of

A g C N

gives ethyl isocyanide as a major product.
Reason (R): Cyanide ion

(C N^{-})

is an ambident nucleophile.

Q. Assertion :Treatment of chloroethane with a saturated solution of

A g C N

gives ethyl isocyanide as the major product. Reason: Cyanide

(C N^{-})

is an ambident nucleophile.

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