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Question

45 g of gaseous mixture of NO2 & N2O gas occupy 22.7 liter at STP. Find the mole % of NO2 in the gaseous mixture.

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Solution

22.7 L is occupied by 1 mole of a substance.
Hence, 45g is the mass of 1 mole or MW of the mixture.
MWmix=(XNO2)(Molecularweightof NO2)+(XN2O)(MolecularweightofN2O)
XNO2+XN2O=1
45=(XNO2)(46)+(1XN2O)(44)
4544=(4644)XNO2
XNO2=12=0.5
Mole% of NO2=%XNO2=50%

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