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Curtius and Hofmann Rearrangements

45 Mixture of...

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45 Mixture of carboxylic acid obtained by the oxidation of hexan-3-one does not yield ?? 1. Methanoic acid 2. Ethanoic acid 3. Propanoic acid 4. Butanoic acid

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Q. The vapour of a carboxylic acid HA when passed over MnO2 at 573 K yields propanone. What is the acid HA?
a) Methanoic acid
b) Ethanoic acid
c) Propanoic acid
d) Butanoic acid

Q. Which of the following decreasing order of acidic strength of

(I)

methanoic acid,

(I I)

(I I I)

propanoic acid, and

(I V)

butanoic acid, is correct?

Q. The acid which reduces Fehling solution is which of the following?
a) Methanoic acid
b) Ethanoic acid
c) Butanoic acid
d) Propanoic acid

Q. How will you convert-

(a) Ethanoic acid into propanoic acid

(b) Propanoic acid into ethanoic acid

The IUPAC name of CH₃CH₂CH₂COOH is:

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Curtius and Hofmann Rearrangements

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