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Question

4HNO3+P4O1010 oC−−−+2N2O5+(HPO3)4
Find out the value of expression |xy| for above reaction
where, x = maximum number of eaqual NO bond length in N2O5.
y = Difference of oxy linkages (P - O - P) between P4O10 and (HPO3)4.

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Solution

x = Maximum number of equal NO bond length in N2O5,
x=4
Terminal NO bonds due to delocalisation


POP linkage in P4O10 is 6 and (HPO3)4 is 4. y=64=2
So, | x - y | = 4 - 2 = 2

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