4mol of carbon dioxide was heated in 1dm3 vessel under conditions which produced at equilibrium 25% dissociation into carbon monoxide and oxygen. The number of moles of carbon monoxide produced :
A
0.5
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B
1.0
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C
2.0
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D
4.0
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Solution
The correct option is B1.0 CO211−α4(1−α)⇌CO0α4α+12O20α/2α/2×4 α=0.25% =0.25 Number of moles of CO=4α=4×0.25=1