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Question

5 g of a gaseous mixture of the He and Ar contained in a 10 l vessel at 27°C exert a pressure of 1 atm (absolute). Determine the mass percentage of He.
Take R=112 Latm/molK

A
10.8
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B
14.2
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C
24.4
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D
74.6
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Solution

The correct option is C 24.4
Let the mass of He be x g, mass of Ar will be (5 - x) g
Moles =massmolas mass
Moles of He=x4
Moles of Ar=5x40
Total moles of gas =x4+5x40
PV=nRTn=PVRT=1×101/12×300=0.4x4+5x40=0.4x=1.22 g
Mass percentage of Helium = 1.225×100=24.4%, Ar=75.6%

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