Given: 5 g of water at 30oC and 5g of ice at −20oC are mixed in a calorimeter, water equivalent of calorimeter is negligible. Specific heat of ice is 0.5cal/(g∘C) and latent heat of ice is 80 cal per gram.
To find the final temperature of the mixture
Solution:
We know,
Specific heat of water, s1=4.18J/(g∘C)=1cal/(g∘C)
As per the given condition,
Mass of ice, m2=5g
Mass of water, m1=5g
Temperature of ice, T2=−20∘C
Temperature of water, T1=30∘C
specific heat of ice, s2=0.5cal/g.°C
latent heat of water L=80calg−1.
Let the final temperature be, T
Here, Heat lost by 5g water = Heat energy needed to change the temperature of ice from –20°C to 0°C + Latent heat needed to change ice at 0°C into water at 0°C + heat absorbed by water (melted ice)
m1s1(T1−T)=m2s2(0−T2)+m2L+m2s2(T−T2)⟹5×1×(30−T)=5×0.5(0−(−20))+5×80+5×1×(T−(0))⟹150−5T=50+400+5T⟹10T=150−50−400⟹T=−30∘C
So the final temperature of the mixture is −30∘C