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Question

5 L of an alkane requires 25 L of oxygen for its complete combustion. If all volumes are measured at constant temperature and pressure, then the alkane is:

A
Butane
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B
Isobutane
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C
Ethane
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D
Propane
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Solution

The correct option is D Propane
CnH2n+2+(3n+12)O2nCO2+(n+1)H2O
5L 25L

Since volume are measured at constant T and P.

Therefore,volume is directly proportional mole.

Since,

nalkane=(23n+1)×no2
Implies that

5=23n+1×25

n=3.
Hence the alkane is propane (C3H8).

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