5 mol of liquid water is compressed from 1 bar to 10 bar at constant temperature. Change in Gibb's energy (ΔG) in Joule is: (Density of water =1000kg/m3)
A
18
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B
225
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C
450
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D
900
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Solution
The correct option is D 900 dG=VdP−SdT at constant T. dG=VdP ∵ for H2O volume will be almost constant on increasing pressure. ∴ΔG=V(ΔP) ΔG=V(P2−P1)=5×18×10−6(101−1)×105Joule=5×18×10−1×102=900Joule.