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Question

50 g of an impure calcium carbonate sample decomposes on heating to give carbon dioxide and 22.4 g calcium oxide. The percentage purity of calcium carbonate in the sample is:

A
60%
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B
80%
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C
90%
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D
70%
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Solution

The correct option is D 80%
CaCO3ΔCaO+CO2
Let pure sample of CaCO3=x grams
Mass of CaO produced after decomposition =22.4 g
Molar mass of CaCO3=100 g/mol
and, Molar mass of CaO=56 g
If 100% is pure, then
100 g CaCO356 g of CaO
Also,y g of CaCO322.4 g of CaO
Dividing these two,
100y=5622.4
y=40 grams
Percentage of purity =MassofpuresampleTotalmassofimpure×100=4050×100=80%

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