50g of an impure calcium carbonate sample decomposes on heating to give carbon dioxide and 22.4g calcium oxide. The percentage purity of calcium carbonate in the sample is:
A
60%
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B
80%
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C
90%
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D
70%
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Solution
The correct option is D80% CaCO3Δ⇌CaO+CO2
Let pure sample of CaCO3=xgrams
Mass of CaO produced after decomposition =22.4g
Molar mass of CaCO3=100g/mol
and, Molar mass of CaO=56g
If 100% is pure, then
100gCaCO3⟶56g of CaO
Also,yg of CaCO3⟶22.4g of CaO
Dividing these two,
100y=5622.4
y=40grams
∴ Percentage of purity =MassofpuresampleTotalmassofimpure×100=4050×100=80%