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Question

50 mL of 0.2 M ammonia solution is treated with 25 mL of 0.2 M HCI. If pKb, of ammonia solution is 4.75, the pH of the mixture will be :

A
3.75
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B
9.25
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C
8.25
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D
4.75
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Solution

The correct option is C 9.25
Number of millimoles of NH3=50mL×0.2M=10mmol
Number of millimoles of HCl=25mL×0.2M=5mmol
5 mmol NH3 will react with 5 mmol HCl to form 5 mmol NH4Cl
105=5 mmol NH3 will remain.
pOH=pKblog[NH4Cl][NH3]
pOH=4.75log5/V5/V
pOH=4.75
pH=14pOH=144.75=9.25

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