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Question

50 ml of 1 M oxalic acid is shaken with 0.5 gm of wood charcoal. The final concentration of the solution after adsorption is 0.5 M. Amount of oxalic acid absorbed per gm of charcoal is:

A
3.45 gm
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B
3.15 gm
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C
6.30 gm
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D
none of these
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Solution

The correct option is C 6.30 gm
No. of moles in 50 ml of 1 M oxalic acid is = 50L1000×1M=0.05 moles of oxalic acid.

After adsorption, remaining moles of oxalic acid=50L1000×0.5M=0.025 moles.
Thus, moles that adsorb on charcoal is =0.050.025=0.025 moles of oxalic acid.

Therefore, 0.025 moles of oxalic acid adsorb on 0.5 g of charcoal.

1 gram of charcoal moles adsorb=0.0250.5=0.05 moles of oxalic acid.

Amount of oxalic acid adsorbed per gram of charcoal = 0.05×126g/mole=6.30grams

Thus, 6.30 g of oxalic acid adsorb per gram of charcoal.

Hence, option C is correct.

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