50 ml of H2O2 solution when titrated with 0.1 M KMnO4 solution in acidic medium, volume required is 40 ml. Volume strength of H2O2 solution is
A
11.2
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B
22.4
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C
1.12
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D
2.24
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Solution
The correct option is D 2.24 Meqv of KMnO4 solution =0.1×5×40meqv=20meqv
So, Meqv of H2O2 solution = 20 meqv ∴M×vol×n−fac=M×50×2=20
So, Molarity of H2O2solution=M=0.2M
So, Volume strength of H2O2 solution =11.2×M=11.2×0.2=2.24volume