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Question

500mL of 0.2M acetic acid are added to 500mL of 0.30M sodium acetate solution. If the dissociation constant of acetic acid is 1.5×105 then pH of the resulting solution is:

A
5.0
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B
9.0
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C
3.0
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D
4.0
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Solution

The correct option is A 5.0
CH3COONa - 500 ml x 0.2 M
CH3COOH - 500 ml x 0.3 M Ka=1.5×105
pH=pKa+log[CH3COONaCH3COOH]
pH=log(1.5×105)+log[0.30.2]=log1.5+5+log1.5=5

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