50cm3 of hydrogen is collected over water at 17∘C and 750 Hg pressure. Calculate the volume of dry gas at S.T.P. The water vapour pressure at 17∘C is 14 mm Hg.
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Solution
PVT=P1V1T1
Here P=750−14=736mm,V=50cm3,T=17+273=290K,P1=760mm,T1=273K