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Bonding in Metal Carbonyls

6 calculate c...

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6 calculate cfse for d6 low spin tetrahedral complex.

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Q. Calculate CFSE values for the following system.

d^{5}

- low spin octahedral:

Δ_{o}

Δ_{t}

represent crystal field splitting energies for d-orbitals for octahedral and tetrahedral geometries respectively, then for

d^{6}

(high spin in both cases), what are CFSE (ignore the pairing energy) respectively?

Q. Low spin tetrahedral complexes are not formed because :

Q. Why are low spin tetrahedral complexes rarely observed?

Why are low spin tetrahedral complexes not formed?

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