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Standard XII
Chemistry
Uses of Slaked Lime
6) G (kJ/mol)...
Question
6) G (kJ/mol) values at 298 K for Ag+ (aq), Cl-(aq) and AgCI (s) are 77,-129 and -109 respectively for the given reaction, Ag (aq) + C (aq) AgCI(s) Then the solubility product of AgCl is
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Q.
For the reaction
A
g
+
(
a
q
)
+
C
l
−
(
a
q
)
⇌
A
g
C
l
(
s
)
; the
Δ
G
o
values for
A
g
+
(
a
q
)
,
C
l
−
(
a
q
)
and
A
g
C
l
(
s
)
are + 77, -129 and -109 kJ mol
−
1
. Write the cell representation of above reaction and calculate
K
s
p
of AgCl at 298 K.
(Multiply the ans by
10
10
)
Q.
calculate
Δ
G
⊖
f
of the reaction :
A
g
⊕
(
a
q
)
+
C
l
⊖
(
a
q
)
→
A
g
C
l
(
s
)
Given :
Δ
G
⊖
A
g
C
l
=
−
109
k
J
m
o
l
−
1
Δ
G
⊖
(
C
l
⊖
)
=
−
129
k
J
m
o
l
−
1
Δ
G
⊖
(
A
g
⊕
)
=
−
77
k
J
m
o
l
−
1
Q.
For the reaction,
A
g
+
(
aq
)
+
C
l
−
(
aq
)
⇌
A
g
C
l
(
s
)
Given:
Species
Δ
G
∘
f
(
kJ/mol
)
A
g
+
(
aq
)
+
77
C
l
−
(
aq
)
−
129
A
g
C
l
(
s
)
−
109
Calculate
E
∘
cell
at
298
K
.
Also find the solubility product of
A
g
C
l
.
Q.
(I) For the reaction,
A
g
+
(
a
q
)
+
C
l
−
(
a
q
)
→
A
g
C
l
(
s
)
Write the cell representation of above reaction and calculate
E
o
at 298 K.
Given:
Species
Δ
G
f
(
k
J
/
m
o
l
)
A
g
+
(
a
q
)
+77
C
l
−
(
a
q
)
-129
A
g
C
l
(
s
)
-109
(II) Calculate the
log
10
K
s
p
(
A
g
C
l
)
at 298 K.
(III) If
6.539
×
10
−
2
g
of metallic zinc is added to 100 ml saturated solution of
A
g
C
l
, find the value of
log
10
[
Z
n
2
+
]
[
A
g
+
]
2
.
(IV)How many moles of Ag will be precipitated in the above reaction?
Given that-
A
g
+
+
e
−
→
Ag;
E
o
=
0.80
V
Z
n
2
+
+
2
e
−
→
Zn;
E
o
=
−
0.76
V
(It was given that Atomic mass of Zn
=
65.39
)
Q.
The standard reduction potentials for two reactions are given below:
AgCl
(
s
)
+
e
-
→
Ag
(
s
)
+
C
l
-
(
aq
)
E
∘
=
0
.22V
A
g
+
(
a
q
)
+
e
−
→
A
g
(
s
)
E
∘
=
0
.80V
The solubility product of
A
g
C
l
under standard conditions of temperature (298 K) is given by:
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