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Question

8.96 L of Cl2 gas which is at STP is mixed with 100 mL of 5 M Ca(OH)2 which reacts as follows:
2Ca(OH)2+2Cl2Ca(OCl)2+CaCl2+2H2O

Find the number of chlorine atoms present in Ca(OCl)2 that is formed.

A
NA
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B
0.5NA
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C
0.2NA
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D
0.4NA
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Solution

The correct option is D 0.4NA
We know that,
nCl2=Volume(L) at STP22.4=8.9622.4=0.4 mol
nCa(OH)2=Molarity×volume (in L)
nCa(OH)2=5×1001000=0.5 mol
Ratio of the reactanting species is 1:1 in the balanced reaction. The one which has fewer moles will be the limiting reagent.
So Cl2 is the limiting reagent and we know that:
nCl2(consumed)2=nCa(OCl)2(produced)1
nCa(OCl)2=0.2 mol
Number of Cl atoms in bleaching powder
=2×0.2×NA=0.4NA

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