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Staggered Conformation

8. Explain di...

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8. Explain dipole moment with direction in cis n2f2

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Dipole moment will be zero in the complexes

I) $[N i (C N)_{4}]^{2 -}$

II) $C i s - [P t (N H_{3})_{2} C l_{2}]$

III) Trans - $[P t (N H_{3})_{2} C l_{2}]$

Q. What is dipole moment? Why do cis-trans isomers have different boiling point?

Q. Assertion :Cis form will always have more boiling point than trans form. Reason: Boiling point depends on dipole moment, greater the dipole moment greater the boiling point.

Q. Assertion :Cis-form of alkene is found to be more polar than the trans-form. Reason: Since the groups are in opposite directions in the trans-form, the dipole moments of bonds cancel each other making trans-form almost non-polar.

The direction of dipole moment is

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