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Standard XII

Chemistry

Reactions of Aryl Amines (Diazo Salts)

8. Show reson...

Question

8. Show resonance in tertiary benzylic and tertiary allylic in diagram

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Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides :

$(C H_{3})_{2} C H C H (C l) C H_{3}$

$C H_{3} C H_{2} C H (C H_{3}) C H (C_{2} H_{5}) C l$

$C H_{3} C H_{2} C (C H_{3})_{2} C H_{2} I$

$(C H_{3})_{3} C C H_{2} C H) (B r) C_{6} H_{5}$

$C H_{3} C H (C H_{3}) C H (B r) C H_{3}$

$C H_{3} C (C_{2} H_{5})_{2} C H_{2} B r$

$C H_{3} C (C l) (C_{2} H_{5}) C H_{2} C H_{3}$

$C H_{3} C H = C (C l) C H_{2} C H (C H_{3})_{2}$

$C H_{3} C H = C H C (B r) (C H_{3})_{2}$

$p - C l C_{6} H_{4} C H_{2} C H (C H_{3})_{2}$

$m - C l C H_{2} C_{6} H_{4} C H_{2} C (C H_{3})_{3}$

$o - B r - C_{6} H_{4} C H (C H_{3}) C H_{2} C H_{3}$

Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:

(i) (CH₃)₂CHCH(Cl)CH₃

(ii) CH₃CH₂CH(CH₃)CH(C₂H₅)Cl

(iii) CH₃CH₂C(CH₃)₂CH₂I

(iv) (CH₃)₃CCH₂CH(Br)C₆H₅

(v) CH₃CH(CH₃)CH(Br)CH₃

(vi) CH₃C(C₂H₅)₂CH₂Br

(vii) CH₃C(Cl)(C₂H₅)CH₂CH₃

(viii) CH₃CH=C(Cl)CH₂CH(CH₃)₂

(ix) CH₃CH=CHC(Br)(CH₃)₂

(x) p-ClC₆H₄CH₂CH(CH₃)₂

(xi) m-ClCH₂C₆H₄CH₂C(CH₃)₃

(xii) o-Br-C₆H₄CH(CH₃)CH₂CH₃

Q. Name the following halides according to

I U P A C

system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:
i)

(C H_{3})_{2} C H C H (C l) C H_{3}

ii)

C H_{3} C H_{2} C H (C H_{3}) C H (C_{2} H_{5}) C l

iii)

C H_{3} C H_{2} C (C H_{3})_{2} C H_{2} I

iv)

(C H_{3})_{3} C C H_{2} C H (B r) C_{6} H_{5}

C H_{3} C H (C H_{3}) C H (B r) C H_{3}

vi)

C H_{3} C (C_{2} H_{5})_{2} C H_{2} B r

vii)

C H_{3} C (C l) (C_{2} H_{5}) C H_{2} C H_{3}

viii)

C H_{3} C H = C (C l) C H_{2} C H (C H_{3})_{2}

ix)

C H_{3} C H = C H C (B r) (C H_{3})_{2}

p - C l C_{6} H_{4} C H_{2} C H (C H_{3})_{2}

xi)

m - C l C H_{2} C_{6} H_{4} C H_{2} C (C H_{3})_{3}

xii)

o - B r - C_{6} H_{4} C H (C H_{3}) C H_{2} C H_{3}

Q. Tertiary nitro compounds cannot show tautomerism because:

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