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Nucleic Acids

84. 1)Why the...

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84. 1)Why the C-Cl bond length in vinyl chloride is smaller than in ethyl chloride? 2)The C -Cl bond length in smaller in chlorobenzene or Benzylchloride and why?

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Q. In comparison to

C - C l

bond in ethyl chloride, the

C - C l

bond in vinyl chloride is:

Q. Give reasons:
(i)

C - C l

bond length in chlorobenzene is shorter than

C - C l

C H_{3} - C l

.
(ii) The dipole moment of chlorobenzene is lower than that of cyclohexyl chloride.
(iii)

S_{N} 1

reactions are accompanied by racemization in optically active alkyl halides.

C - C l

bond of chlorobenzene in comparison to

C - C l

bond of methyl chloride is:

(C - C l)

C H_{2} = C H - C l

(vinyl chloride) is stabilised in the same way as in:

C - C l

C H_{2} = C H - C l

(vinyl chloride) is stabilized in the same way as in:

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