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Linear Combination of Atomic Orbitals

85. Do all of...

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85. Do all of the atomic orbitals participate in the formation of molecular orbitals?

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Q. According to the band theory, increase in number of atoms participating in crystal formation leads to ________ in number of molecular orbitals containing electrons.

Q. According to MOT (Molecular Orbital Theory), the molecular orbitals are formed by mixing of atomic orbitals through LCAO (linear combination of atomic orbitals). The correct statement (s) about molecular orbitals is/are Statement (a) : bonding molecular orbitals are formed by addition of wave-functions of atomic orbitals of same phase Statement (b) : anti-bonding molecular orbitals do not take part in bond formation because they belong to inner shells Statement (d) : anti-bonding molecular orbitals provide stability to molecules while bonding molecular orbitals make the molecules unstable.

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Q. During the formation of a molecular orbital from atomic orbitals of the same atom probability of electron density is -

In the valence bond theory, hybridization of orbitals is an integral part of the bond formation. Hybridisation consists of mixing or a linear combination of the "pure" atomic orbitals in such a way as to form new hybrid orbitals such as

s p, s p^{2}, s p^{3}, s p^{3} d, s p^{3} d^{3}

Which of the following atomic orbitals does not participate in trigonal bipyramidal hybridization i.e.

s p^{3} d

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Linear Combination of Atomic Orbitals

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