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Question

87Rb undergoes β-decay (t1/2=4.7×1010year) to form 87Sr. An analysis of the rock sample shows relative number of 87Sr and 87Rb atoms 0.052:1. If all the 87Sr is formed from β-decay of 87Rb, The age of the rock is :

A
[2.21×109year]
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B
[3.43×109year]
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C
[4.13×109year]
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D
none of these
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Solution

The correct option is C [3.43×109year]
The beta decay follows first-order kinetics.
Rate constant, k= 0.693t1/2
Given, t1/2=4.7×1010 years
k=0.6934.7×1010years
k=1.47×1011
Also, t=2.303k×logNoNt
No=1.052
Nt=1.0
t=2.3031.47×1011×log1.0521.0
Hence, the age of the rock, t=3.43×109 years.

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