8g of NaOH was dissolved in 1 L of a solution containing one mole of acetic acid CH3COOH and one mole of sodium acetate CH3COONa. Find the pH of the resulting solution.
The dissociation constant for CH3COOH is 1.8×10−5.
A
6.88
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B
4.92
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C
3.68
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D
5.76
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Solution
The correct option is B 4.92 Concentration of NaOH=840=0.2molL−1 CH3COOH(aq)+NaOH(aq)→CH3COONa(aq)+H2O(l)Initial:10.210Equilibrium:(1−0.2)01+0.20.2 pKa=−log(Ka)pKa=−log(1.8×10−5)pKa=(5−0.26)=4.74