9.2g N2O4 is heated in a 1L vessel till equilibrium state is established N2O4(g)⇌2NO2(g) In equilibrium state 50%N2O4 was dissociated, equilibrium constant will be.
A
0.1
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B
0.4
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C
0.3
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D
0.2
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Solution
The correct option is A0.2 N2O4⇌2NO2
For 92g of N2O4 we get, 2×46g of NO2
For 9.2g of N2O4 we get, 2×4.6g of NO2
Only 50% of N2O4 is dissociated,
For 4.6g of N2O4 we get, 2×2.3g of NO2
So in equilibrium state 4.6g of N2O4 and 2×2.3=4.6g of NO2 is present.