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Question

9.2g N2O4 is heated in a 1L vessel till equilibrium state is established N2O4(g)2NO2(g)
In equilibrium state 50% N2O4 was dissociated, equilibrium constant will be.

A
0.1
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B
0.4
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C
0.3
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D
0.2
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Solution

The correct option is A 0.2
N2O42NO2
For 92g of N2O4 we get, 2×46g of NO2
For 9.2g of N2O4 we get, 2×4.6g of NO2

Only 50% of N2O4 is dissociated,
For 4.6g of N2O4 we get, 2×2.3g of NO2
So in equilibrium state 4.6g of N2O4 and 2×2.3=4.6g of NO2 is present.

[N2O4]=(4.6/92)/1=0.05
[NO2]=(4.6/46)/1=0.1
Equilibrium constant is Productsreactants
Kc=[NO2]2[N2O4]=0.01/0.05=0.2

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