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Question

9.2g of N2O4(g) is taken in a closed one litre vessel and heated till the following equilibrium is reached
N2O4(g)2NO2(g)
At equilibrium 50% of N2O4(g) is dissociated. What is the equilibrium constant?
[in mole lit1] [M.wt. of N2O4 is 92]

A
0.1
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B
0.2
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C
0.4
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D
2
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Solution

The correct option is B 0.2
9.2 g of N2O4(g) corresponds to 9.292=0.1 moles
Out of these 0.05 moles (50% of 0.1 moles) dissociate to form 2×0.05=0.1 moles of NO2(g)
The equilibrium constant is Kc=[NO2]2N2O4=(0.1)20.05=0.2
Hence the correct option is B.

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