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Acidity of Carboxylic Acids

9. give reaso...

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9. give reason for the following order of the acidic strength of the following - H3PO2> H3PO3> H3PO4

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Q. What is the order of acidic strength of

H_{3} P O_{4}, H_{3} P O_{3}, H_{3} P O_{2}

What is the acidic strength order of $H_{3} P O_{2}$ , $H_{3} P O_{3}$ , $H_{3} P O_{4}$ ? Why ?

Q. Assertion :There is a very little difference in acidic strengths of

H_{3} P O_{4}, H_{3} P O_{3}

H_{3} P O_{2} .

Reason: Number of unprotonated oxygen

(= O)

responsible for increase of acidic strength due to inductive effect remains the same.

Q. The order of the oxidation state of the phosphorous atom in

H_{3} P O_{2}, H_{3} P O_{4}, H_{3} P O_{3}

H_{4} P_{2} O_{6}

Q. Which of the following is a true statement for the acids of phosphorus:

H_{3} P O_{2}, H_{3} P O_{3}

H_{3} P O_{4}

?

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