Oxidation of ...

Oxidation of Alkynes

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Q. 17. 1-butyne on oxIdation with hot alkaline KMnO4 would yield which of the following as end product? 1. CH3CH2CH2COOH 2. CH3CH2COOH 3. CH3CH2COOH + CO2 + H2O 4. CH3CH2COOH + HCOOH

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In the following series of reactions

$N a C l + A \to B + H C l$ , $B + c o k e \to N a_{2} S + C O$

$N a_{2} S + C \to N a_{2} C O_{3} + C a S A$ , $B$ and $C$ are respectively

H2SO4, Na2SO4, CaCO3
HCl, Na2CO3, H2S
H2S, HCl, CO2
H2SO4, Na2CO3, H2O

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$P h C \equiv C - C H_{3} H_{3} O^{+} / H g^{+ 2} - ------- \to A$ . Then 'A' is

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Q. Propose structures for hydrocarbons that give the following products on oxidative cleavage by

K M n O_{4}

O_{3}

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C a C_{2} + H_{2} O \to A H_{2} S O_{4} / H g S O_{4} - -------- \to B

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Identify A and B in the given reaction

$C_{2} H_{2} a n d C H_{3}$
$C H_{4} a n d H C O O H$
$C_{2} H_{4} a n d C H_{3} C O O H$
$C_{2} H_{2} a n d C H_{3} C O O H$

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